Edata2: a Fortran Iv Computer Program for Processing Wavelength- And/or Energy-dispersive Electron Microprobe Analyses
نویسنده
چکیده
The development of EDATA2 was stimulated by the proliferation of mixed energy dispersive/wavelength dispersive equipped electron microprobes. For such systems to be operated most efficiently and conveniently, a data reduction program is required that can handle energy-dispersive, wavelength-dispersive, or a mixture of both kinds of data. This requirement has become particularly pressing with the widespread introduction of a high degree of automation, which permits either kind of data to be gathered rapidly and reliably. If the reduction of data to give the compositional information ultimately required is not to present a bottleneck, software must be versatile, running times short, and costs low. In the development of EDATA2 (Fig. 1) the design philosophy of its predecessor, "EDATA," was retained in that an automatic rather than an interactive program was constructed. In any laboratory where an appreciable part of the operation involves producing large numbers of analyses, it is desirable that minimal intervention be required during data processing. EDATA was developed to process only energy-dispersive analyses, and was limited to handling analytical data for elements of atomic number 11 (Na) to 30 (Zn), plus Zr and Ba. These elements cover the compositions of most silicates, as well as many other minerals. However, EDATA2 permits the specification of any suite of up to 22 analyzed elements (from Z = 9 to 92). An empirical expression for the relationship of continuum intensity to atomic number, continuum energy, and accelerating potential has now been reinvestigated for an accelerating voltage of 15 kV, continuum energies up to 10 keV, and for atomic numbers up to 92; the following new expression was obtained:
منابع مشابه
Electron Microprobe Analysis Lecture Notes
The electron microprobe provides a complete micrometer-scale quantitative chemical analysis of inorganic solids. The method is nondestructive and utilizes characteristic Xrays excited by an electron beam incident on a flat surface of the sample. This course provides an introduction to the theory of X-ray microanalysis through wavelength and energy dispersive spectrometry (WDS and EDS), ZAF matr...
متن کاملA Scheme for Fully Quantitative Energy Dispersive Microprobe Analysis
A procedure and program are described for rapid, economical and simple production of fully quantitative, multi-element analyses from energy dispersive microprobe data. Methods are outlined for background shaping and scaling, comprehensive overlap correction, and adjustment for instrumental drift. Program facilities include the output of all coefficients required, built-in standard data, the opt...
متن کاملElectron Microprobe Analysis by Wavelength Dispersive Spectrometry on the JEOL JXA-733 Superprobe
The electron microprobe provides a complete micron-scale quantitative chemical analysis of inorganic solids. The method is nondestructive and utilizes characteristic x-rays excited by an electron beam, incident on a flat surface of the sample. This course will provide an introduction to the theory of x-ray microanalysis by wavelength and energy dispersive spectrometry (WDS and EDS), ZAF matrix ...
متن کاملSynthesis of REE and Y phosphates by Pb-free ß ux methods and their utilization as standards for electron microprobe analysis and in design of monazite chemical U-Th-Pb dating protocol
(REE,Y) phosphates were synthesized in a 1 atm furnace by ß ux-growth methods involving Pb-free ß uxes. Microcrystalline (REE,Y) phosphate was precipitated from a solution of (REE,Y) chlorides or nitrates plus ammonium dihydrogen phosphate, and mixed with a M2CO3 (M = Li or Na)-MoO3 ß ux (75:25:2 molar ratio M2CO3:MoO3:REEPO4). Crystal growth was achieved over the temperature range 1350870 °C,...
متن کاملThe Atomic Number Dependence of the X-Ray Continuum Intensity and the Practical Calculation of Background in Energy Dispersive Electron Microprobe Analysis
Computer fitting techniques have been used to derive a new expression for the relationship between X-ray continuum intensity and atomic number for a range of electron accelerating potentials up to 25 kV, continuum energies up to 10 keV and average atomic numbers up to thirty. A practical approach to background corrections in energy dispersive electron microprobe analysis, which utilizes this ex...
متن کامل